Item type:Thesis, Open Access

Totalsynthesen von (+)-Elevenol, (+)-Przewalskin und (+)-Nivetetracyclat A

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Philipps-Universität Marburg

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Abstract

This work describes the first successful and entantioselective synthesis of (+)-Elevenol and (+)-Przewalskin. Elevenol was synthesized in 14 steps with an overall yield of 7%. Coming from (+)-Elevenol a defunctionalization lead to the construction of another dinorditerpene (+)-Przewalskin in 17 steps and an overall yield of 3%. The first successful enantioselective total synthesis of Nivetetracylate A is described in this work. Nivetetracyclate A was synthesized in 17 linear steps with an overall yield of 0.9%.

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Blitz, Michel: Totalsynthesen von (+)-Elevenol, (+)-Przewalskin und (+)-Nivetetracyclat A. : Philipps-Universität Marburg 2019-10-16. DOI: https://doi.org/10.17192/z2019.0113.

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This item has been published with the following license: In Copyright