Item type:Thesis, Open Access

Metal complexes with non-innocent N-donor Ligands: molecular and electronic structures, reactivity, and application

Thumbnail Image

Files

dmmk.pdf (5.98 MB)

Date

2006-09-08

Authors

Publisher

Philipps-Universität Marburg
DOI

Supervisors

Abstract

The present work comprises different aspects of coordination chemistry of non-innocent, or redox active, ligands. The most attention is given to the complexes of late transition metals as well as phthalocyanines of alkaline earth metals. The dissertation covers synthesis of complexes with non-innocent ligands and investigation of their molecular and electronic structures by set of methods including X-ray crystallography, EPR, NMR and electronic spectroscopy, electro- and magnetochemistry. Application such of complexes as catalysts for olefin polymerization or one-dimensional conducting materials is presented. I hope this work will be of interest as for synthetic chemists as well as for physical chemists having interest in application of variety of spectroscopic methods to allow deep understanding of coordination compounds with sophisticated electronic structures.

Review

Metadata

Contributors
Supervisor:
Dates
Created: 2006Issued: 2006-09-08Updated: 2011-08-10
DOI
https://doi.org/10.17192/z2006.0147
Faculty
Fachbereich Chemie
Publisher
Philipps-Universität Marburg
Language
eng
Data types
DoctoralThesis
Keywords
Ethylene polymerizationCatalystsElectronic structureNickelConductorsCrystallographyPalladiumEPR spectroscopyCobaltIronMagnetochemistryCopperParamagnetism
DFG-subjects
PhthalocyaninesRedox activeAlkaline earth metalsCoordination chemistryRadicalsNon-innocent ligandsLate transition metals
DDC-Numbers
540
License
https://rightsstatements.org/vocab/InC-NC/1.0/
URI
https://open.uni-marburg.de/handle/10.17192/z2006.0147
show more
Khusniyarov, Marat: Metal complexes with non-innocent N-donor Ligands: molecular and electronic structures, reactivity, and application. : Philipps-Universität Marburg 2006-09-08. DOI: https://doi.org/10.17192/z2006.0147.

License

item.page.license.under-copyright
This item has been published with the following license: In Copyright