Item type:Thesis, Open Access

Synthese zweifach-koordinierter, quasilinearer Übergangsmetall(II/I)-Komplexe

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Date

2022-09-07

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Philipps-Universität Marburg
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Abstract

The present work deals with the synthesis and reactivity of the young and relatively unexplored substance class of (quasi-)linear 3d-metal(I) complexes. Due to the electronically and coordinatively unsaturated metal centers, the compounds are highly reactive as demonstrated in initial studies based on their reactivity towards small molecules and substrates. Insights into their magnetic behavior also indicate promising potential. However, only rare examples have been described in literature so far. This work contributes to the general understanding of the structural as well as magnetic properties and reactivities of silylamide-based metal(I) complexes and their metal(II) precursors. In addition, the spectrum of linear 3d metal(II) complexes has been extended to a complex with a phosphorus-based ligand system.

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Dates
Created: 2021Issued: 2022-09-07Updated: 2022-09-07
DOI
https://doi.org/10.17192/z2022.0074
Faculty
Fachbereich Chemie
Publisher
Philipps-Universität Marburg
Language
ger
Data types
DoctoralThesis
Keywords
Anorganik
DFG-subjects
Quasilinearität3d-ÜbergangsmetalleKomplexe
DDC-Numbers
540
License
https://creativecommons.org/licenses/by-nc-nd/4.0/
URI
https://open.uni-marburg.de/handle/10.17192/z2022.0074
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Weller, Ruth: Synthese zweifach-koordinierter, quasilinearer Übergangsmetall(II/I)-Komplexe. : Philipps-Universität Marburg 2022-09-07. DOI: https://doi.org/10.17192/z2022.0074.

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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 - CC BY NC ND
Except where otherwised noted, this item's license is described as Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 - CC BY NC ND