Item type:Thesis, Open Access

Quantenchemische Untersuchungen an zweiwertigen E(0)-Verbindungen der 14. Gruppe und deren Analoga der Gruppe 15

Thumbnail Image

Files

dsk.pdf (17.34 MB)

Date

2011-12-19

Authors

Publisher

Philipps-Universität Marburg
DOI

Supervisors

Abstract

In analogy to the transition metals carbon atoms can be stabilized by σ-donor ligands. The bonding analysis of such molecules and the calculated reactivities toward Lewis acids show that these molecules have two lone pairs at the carbon atom and thus react as double Lewis bases. The bonding description can be extended to the corresponding silicon, germanium, tin and lead compounds and their analogs of the group 15. The calculated properties strongly depend on the ligands and show that the transitions between carbones, carbenes and heterocumulenes are smooth.

Review

Metadata

Contributors
Supervisor:
Dates
Created: 2011Issued: 2011-12-19Updated: 2011-12-21
DOI
https://doi.org/10.17192/z2011.0645
Faculty
Fachbereich Chemie
Publisher
Philipps-Universität Marburg
Language
ger
Data types
DoctoralThesis
Keywords
carbonesCarbonedonor stabilized carbon atomsmain group complexescarbonbonding analysis
DFG-subjects
QuantenchemieChemische BindungHauptgruppenelementkomplexeKohlenstoff
DDC-Numbers
540
License
https://rightsstatements.org/vocab/InC-NC/1.0/
URI
https://open.uni-marburg.de/handle/10.17192/z2011.0645
show more
Klein, Susanne (136666426): Quantenchemische Untersuchungen an zweiwertigen E(0)-Verbindungen der 14. Gruppe und deren Analoga der Gruppe 15. : Philipps-Universität Marburg 2011-12-19. DOI: https://doi.org/10.17192/z2011.0645.

License

item.page.license.under-copyright
This item has been published with the following license: In Copyright