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Durch N-heterozyklische Carbene stabilisierte Kalium-Phosphinidenide zur Synthese von Hauptgruppen-substituierten Phosphinidenen

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2020-04-06

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Philipps-Universität Marburg
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Abstract

During this work the possibility of synthesizing main group substituted phosphinidenes starting from NHC-stabilized phosphinidenides was investigated. Herein, phosphinidenides of the form [(NHC)PK] were used (NHC = SIMes, SIDipp). In this work group 13, 14 and 15 substituted NHC-stabilized phosphinidenes were synthesized and characterized by means of x-ray structure analysis, 1H-, 13C-, 31P-NMR, IR-spectroscopy and elemental analysis. In addition, various NHC-stabilized K/P-clusters were synthesized, which show solubility in toluene, in contrast to the NHC-stabilized phosphinidenides.

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Dates
Created: 2019Issued: 2020-04-06Updated: 2020-04-06
Faculty
Fachbereich Chemie
Language
ger
Data types
DoctoralThesis
Keywords
PhosphinidenephsophinidenesPhosphinidenidcarbeneNHCphosphinidenideNHCCarben
DFG-subjects
PhosphinidenidPhosphinideneCarbenNHC
DDC-Numbers
540
License
https://rightsstatements.org/vocab/InC-NC/1.0/
URI
https://open.uni-marburg.de/handle/10.17192/z2019.0482
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Balmer, Markus: Durch N-heterozyklische Carbene stabilisierte Kalium-Phosphinidenide zur Synthese von Hauptgruppen-substituierten Phosphinidenen. : Philipps-Universität Marburg 2020-04-06. DOI: https://doi.org/10.17192/z2019.0482.

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This item has been published with the following license: In Copyright