Item type:Thesis, Open Access

Alpha-Diiminkomplexe in ionischen Flüssigkeiten - Immobilisierung durch Sulfonatanker und solvatochrome Effekte

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Date

2012-02-16

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Philipps-Universität Marburg
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Abstract

The main theme of this thesis was to connect the two major topics "Ionic Liquids (ILs)" and "complexes of conjugated 1,4-diazaligands" by testing new synthetic concepts within four loosely connected projects. Project I: Guanidinium methylcarbonates were established as powerful intermediates in the metal- and halide-free synthesis of guanidinium-based ILs. Project II: Diazabutadiene ligands bearing sulfonate tags and their transition metal complexes were studied in detail and were shown to be well immobilized in ILs. Project III: A sulfonate-tagged dipyridophenazine ligand was evaluated as starting material for Ru(II) complexes in the context of dye-sensitized solar cells. Project IV: Mo(0)-DAD-Tricarbonyl complexes were synthesized with a variety of neutral as well as anionic coligands. They were studied with respect to their structural and solvatochromic properties.

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Dates
Created: 2011Issued: 2012-02-16Updated: 2012-03-19
DOI
https://doi.org/10.17192/z2012.0070
Faculty
Fachbereich Chemie
Publisher
Philipps-Universität Marburg
Language
ger
Data types
DoctoralThesis
Keywords
Sulfonate tagsGuanidinium saltsSolvatochromismIonic liquids
DFG-subjects
ImmobilisierungIonische FlüssigkeitSuSolvatochromieHomogene KatalysePräparative anorganische ChemieAnkergruppeAnorganische Chemie
DDC-Numbers
540
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https://rightsstatements.org/vocab/InC-NC/1.0/
URI
https://open.uni-marburg.de/handle/10.17192/z2012.0070
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Oelkers, Benjamin (1019185996): Alpha-Diiminkomplexe in ionischen Flüssigkeiten - Immobilisierung durch Sulfonatanker und solvatochrome Effekte. : Philipps-Universität Marburg 2012-02-16. DOI: https://doi.org/10.17192/z2012.0070.

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