Alpha-Diiminkomplexe in ionischen Flüssigkeiten - Immobilisierung durch Sulfonatanker und solvatochrome Effekte
Loading...
Files
Date
Authors
Publisher
Philipps-Universität Marburg
Abstract
The main theme of this thesis was to connect the two major topics "Ionic Liquids (ILs)" and "complexes of conjugated 1,4-diazaligands" by testing new synthetic concepts within four loosely connected projects.
Project I: Guanidinium methylcarbonates were established as powerful intermediates in the metal- and halide-free synthesis of guanidinium-based ILs.
Project II: Diazabutadiene ligands bearing sulfonate tags and their transition metal complexes were studied in detail and were shown to be well immobilized in ILs.
Project III: A sulfonate-tagged dipyridophenazine ligand was evaluated as starting material for Ru(II) complexes in the context of dye-sensitized solar cells.
Project IV: Mo(0)-DAD-Tricarbonyl complexes were synthesized with a variety of neutral as well as anionic coligands. They were studied with respect to their structural and solvatochromic properties.
Review
Metadata
License
This item has been published with the following license: In Copyright