Item type:Thesis, Open Access

Entwicklung Zirconocen-basierter Methoden zur C,C-Bindungsknüpfung und deren Anwendung in der Totalsynthese von (+)-Guignardon A

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2024-06-18

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Philipps-Universität Marburg
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Abstract

To solve problems in the total synthesis of guignardon A, two methods were developed and their usability investigated. Firstly, the stereoselective rhodium-catalysed 1,4-addition of alkenylzirconocenes to cyclic enones with subsequent transformation of the intermediate enolates and, secondly, the palladium-catalysed cross-coupling of alkyl- and arylzirconocenes to alkenyl- and arylnonaflates.

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Dates
Created: 2023Issued: 2024-06-18Updated: 2024-06-18
DOI
https://doi.org/10.17192/z2023.0663
Faculty
Fachbereich Chemie
Publisher
Philipps-Universität Marburg
Language
ger
Data types
DoctoralThesis
Keywords
Rhodium-katalysierte 1,4-AdditionTotalsynthese von Guignardon APalladium-catalyzed cross couplingPalladium-katalysierte KreuzkupplungRhodium-catalyzed 1,4-additionTotal synthesis of guignardone A
DFG-subjects
TotalsyntheseMethodenentwicklungGuignardonZirkonocene
DDC-Numbers
540
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https://rightsstatements.org/vocab/InC-NC/1.0/
URI
https://open.uni-marburg.de/handle/10.17192/z2023.0663
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Weidemüller, Stephan Werner: Entwicklung Zirconocen-basierter Methoden zur C,C-Bindungsknüpfung und deren Anwendung in der Totalsynthese von (+)-Guignardon A. : Philipps-Universität Marburg 2024-06-18. DOI: https://doi.org/10.17192/z2023.0663.

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This item has been published with the following license: In Copyright