Binary Zintl anions of the tetrel and pentel elements have been synthesized. The work's focus is on the synthesis and derivatization of Zintl anions and multi-metallic clusters of the elemental combinations of germanium/phosphorus and germanium/arsenic. Novel binary Zintl anions and multi-metallic clusters with the elements vanadium, niobium, tantalum, and cadmium are presented.
Zintlphosphoruscluster anionPolyanionpolyanionsfunctionalisationmain group elementsarsenichetero-atomicHauptgruppenchemiegermaniumAnorganische ChemiederiClusterZintlclustermulti-metallic
Mitzinger, Stefan Martin Jürgen: Synthesis and Derivatisation of Hetero-Atomic Zintl Anions and Multi-Metallic Clusters of the Tetrel and Pentel Elements. : Philipps-Universität Marburg 2018-04-05. DOI: https://doi.org/10.17192/z2018.0106.