Item type:Thesis, Open Access

Organische Funktionalisierung sowie intramolekulare Verknüpfung von Zinnchalkogenid-Clustern zur Darstellung von organisch-anorganischen Hybridverbindungen

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Date

2014-07-23

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Philipps-Universität Marburg
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Abstract

This work further explored and expanded the chemistry of organo-functionalized tinchalcogenide clusters of the general composition [(RfSn)xEy] (E = S, Se; Rf = organic moiety with functional group). The main focus was put on the formation of binary and ternary metalchalcogenide complexes that are decorated with functional organic ligands, expanding the so far known pool of organic rests (R = COOH, C(O)Me, CN) as outlined in the following. According to the plan of the project, the investigated organic ligands should bear the potential to inter- or intramolecularly link cluster units to result in organic-inorganic hybrid compounds. Therefore, a direct connection of suitable molecules to the tin atom of the Sn/S clusters (usually introduced into the cluster precursor RfSnCl3), or extension of existing ligands spheres to form modified clusters [(Rf’Sn)4S6] was targeted.

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Dates
Created: 2014Issued: 2014-07-23Updated: 2014-07-23
DOI
https://doi.org/10.17192/z2014.0368
Faculty
Fachbereich Chemie
Publisher
Philipps-Universität Marburg
Language
ger
Data types
DoctoralThesis
Keywords
clustermetalorganic chemistrytinligandcrystallographychalcogens
DFG-subjects
ChalkogeneLigandZinnClusterKristallographieMetallorganische Chemie
DDC-Numbers
540
License
https://rightsstatements.org/vocab/InC-NC/1.0/
URI
https://open.uni-marburg.de/handle/10.17192/z2014.0368
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Barth, Beatrix E. K. (1053948492): Organische Funktionalisierung sowie intramolekulare Verknüpfung von Zinnchalkogenid-Clustern zur Darstellung von organisch-anorganischen Hybridverbindungen. : Philipps-Universität Marburg 2014-07-23. DOI: https://doi.org/10.17192/z2014.0368.

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