Item type:Thesis, Open Access

Über die Darstellung und Reaktivität von Bis(trimethylsilyl)pnictogeniden und Dihydrogenpnictogeniden

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2025-05-15

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Philipps-Universität Marburg
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Abstract

The main purpose of this dissertation was to synthesise bis(trimethylsilyl)pnictogenides and dihydrogenpnictogenides and, based on this, to study their reactivity in a variety of areas. The results of the work are divided into four chapters for a better overview. First, the synthesis of the dihydrogenpnictogenides is reported and their reactivity is investigated in more detail. Then, the solid state studies of phosphane, arsane and stibane are summarized. Subsequently, the results of salt elimination reactions with [(Dipp2NacNac)MCl] systems are reported and finally, the preparation of LEWIS acid-base adducts starting from compounds of the type [KPn(SiMe3)2] or [K(18c6)PnH2], as well as related compounds and trialkyl triels is explained in more detail. The present work comprises a total of 75 novel compounds, which were characterized in more detail using X-ray structural analysis, NMR spectroscopy, elemental analysis and infrared spectroscopy. This list does not include compounds that were synthesized as part of collaborative projects with other working groups.

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Dates
Created: 2025Issued: 2025-05-15Updated: 2025-05-15
DOI
https://doi.org/10.17192/z2025.0113
Faculty
Fachbereich Chemie
Publisher
Philipps-Universität Marburg
Language
ger
Data types
DoctoralThesis
DDC-Numbers
540
License
https://creativecommons.org/licenses/by-nc-nd/4.0/
URI
https://open.uni-marburg.de/handle/10.17192/z2025.0113
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Dollberg, Kevin: Über die Darstellung und Reaktivität von Bis(trimethylsilyl)pnictogeniden und Dihydrogenpnictogeniden. : Philipps-Universität Marburg 2025-05-15. DOI: https://doi.org/10.17192/z2025.0113.

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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 - CC BY NC ND
Except where otherwised noted, this item's license is described as Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 - CC BY NC ND