Item type:Thesis, Open Access

Pentafluorphenylamide - von interessanten Liganden in der Seltenerdmetallchemie zu neuen Anionen in ionischen Flüssigkeiten

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Date

2009-06-30

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Philipps-Universität Marburg
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Abstract

The work deals with different aspects of the chemistry of pentafluorophenylamides. The applicability of these weakly basic N-donors both for the design of strongly Lewis acidic metal complexes and for the use as anions in ionic liquids. Thereby both bis(pentafluorophenyl)amide and a ligand derived from bisnephthylamide were used to generate complex compounds containing metal cations of the rare earth metals. Some of these compounds were tested in the ring opening polymerisation of epsilon-caprolactone. Furthermore a series of hydrophobic ionic liquids were synthesized containing pentafluorophenylamidoanions.

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Dates
Created: 2008Issued: 2009-06-30Updated: 2011-08-10
DOI
https://doi.org/10.17192/z2009.0127
Faculty
Fachbereich Chemie
Publisher
Philipps-Universität Marburg
Language
ger
Data types
DoctoralThesis
Keywords
Ionic liquidCaprolactoneAlkaline earth metalRare earth metalAmido
DFG-subjects
ErdalkalimetallAmideCaprolacton Ionische FlüssigkeitSeltenerdverbindungen
DDC-Numbers
540
License
https://rightsstatements.org/vocab/InC-NC/1.0/
URI
https://open.uni-marburg.de/handle/10.17192/z2009.0127
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Linder, Thomas: Pentafluorphenylamide - von interessanten Liganden in der Seltenerdmetallchemie zu neuen Anionen in ionischen Flüssigkeiten. : Philipps-Universität Marburg 2009-06-30. DOI: https://doi.org/10.17192/z2009.0127.

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This item has been published with the following license: In Copyright