Item type:Article, Open Access

The Bismuth Phosphanides Bi(PR2)3: Sources of Phosphanyl Radicals, P-Inversion, and Reversible Olefin Insertion

Abstract

The isolation of simple bismuth phosphanides is presented for the first time. These compounds release phospohanyl radicals, allowing for P-P coupling and the insertion of olefins and CS2 into Bi-P bonds. The olefin insertion reactions are reversible.

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Reith, Sascha; Oberdorf, Kai; Martínez, Sebstián; Landgraf, Jann B.; Ahrens, Alena; Jakobi, Felix; Xie, Xiulan; Lichtenberg, Crispin: The Bismuth Phosphanides Bi(PR2)3: Sources of Phosphanyl Radicals, P-Inversion, and Reversible Olefin Insertion. In: Chemical Science. Vol. 17, Issue 10, Jg. (), S. 5183-5191. DOI: https://doi.org/10.17192/openumr/1082.

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Except where otherwise noted, this item's license is described as Attribution 4.0 International

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Reith, Sascha
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