Diaryl Bismuthides and Acyl Bismuthanes Enable Visible-Light-Induced Reversible Carbon Monoxide Insertion and Extrusion

Simple anionic bismut(I) compounds grant access to bismuth acyl compounds for the first time. These compounds reversible eliminate/insert carbon monoxide upon irradiation with visible light. This mimicks important elementary reactions that have been realized for transition metal chemistry now for the first time in light-driven main group chemistry .

Metadata

Relations

Is version of: https://doi.org/10.1038/s41467-025-66412-5

DOI

https://doi.org/10.17192/openumr/1079

Publisher

Springer Nature

Language

en

Data types

JournalArticle

Keywords

bismuth acylreversible insertion/extrusioncarbon monoxidevisible-light driven main group chemistry

License

Attribution 4.0 International

URI

https://open.uni-marburg.de/handle/openumr/11616

Geist, Felix; Narz, Benedikt; Boguslawski, Darian; Dunaj, Tobias; Reith, Sascha; Poater, Jordi; Lichtenberg, Crispin: Diaryl Bismuthides and Acyl Bismuthanes Enable Visible-Light-Induced Reversible Carbon Monoxide Insertion and Extrusion. In: Nature Communication 16, 10234, Jg. (), S. 1-7. DOI: https://doi.org/10.17192/openumr/1079.