Item type:Article, Open Access

Alkyl Bismuth Cations: Synthesis, Characterization, and Application as Z-Type Ligands

Abstract

Dialkyl(bismuth)cations are accessed and characterized. They grant access to rare examples of Bi-Pt metal-only Lewis pairs. Cycloproyl substituents undergo Bi-to-Pt transfer along with ring-opening to yield allyl platinum species.

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Schwarzmann, Johannes; Nitzsche, Joel; Slopianka, Cissie; Hartmann, Liva; Augustinov, William; Gagnon, Alexandre; von Hänisch, Carsten; Lichtenberg, Crispin: Alkyl Bismuth Cations: Synthesis, Characterization, and Application as Z-Type Ligands. In: Chemistry – A European Journal. 32, no. 18 (2026): e70803, Jg. (), S. 1-9. DOI: https://doi.org/10.17192/openumr/1084.

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